From
Microshaft website:
How do I remove a drive from a pool?
If you created a pool in Windows 10 or upgraded an existing pool, you'll be able to remove a drive from it. The data stored on that drive will be moved to other drives in the pool, and you'll be free to use the drive for something else.
Go to the taskbar, type Storage Spaces in the search box, and select Storage Spaces from the list of search results.
Select Change settings > Physical drives to see all the drives in your pool.
Find the drive you want to remove and select Prepare for removal > Prepare for removal. Leave your PC plugged in until the drive is ready to be removed. This could take several hours, depending on how much data you have stored there.
(Optional) To speed up drive preparation, prevent your PC from going to sleep. Type Power and sleep in the search box on the taskbar, then select Power & sleep settings. Under When plugged in, PC goes to sleep after, select Never.
When the drive is listed as Ready to remove, select Remove > Remove drive. Now, you can disconnect the drive from your PC.
Note
If you run into problems when you try to prepare the drive for removal, it might be because you don't have enough free space in the pool to store all the data from the drive you want to remove. Try adding a new drive to the pool that's as large as the drive you plan to remove and then try again.