I installed kodi right now on windows 10, then searching here C:\Program Files\Kodi in every subfolder for the file guisettings.xml but there is no file with this name , theoretically that file sould be into the userdata folder, but inside it I see only: the file RssFeeds.xml and the folder iOS.
Just to expand on it a bit - in the table in section 1 of the wiki page ronie linked to, "Windows UWP" is the store version and "Windows" is the standard version (the one downloaded from your link above).
%APPDATA%\Kodi\userdata (from the table) and %LOCALAPPDATA%\AppData\Roaming\Kodi\userdata (from your post) should point to the same place.