Which addon version are you using - latest addon should be able to properly detect the 64 bit runtime (how annoying if it still doesn't)
AppleTV4/iPhone/iPod/iPad: HowTo find debug logs and everything else which the devs like so much: click here
HowTo setup NFS for Kodi: NFS(wiki)
HowTo configure avahi (zeroconf): Avahi_Zeroconf(wiki)
READ THE IOS FAQ!: iOS FAQ(wiki)