Not really, windows desktop only offers software raid 0. The various server versions offer other versions of raid.
For clarification
raid 0, combines two disks into one
raid 1, mirroring with no parity. Been ages since I've done raid one, but don't you need both volumes for it to work. I.E. one drive fails you need to rebuild the array before reuse i think.
So windows desktop just combines two drives into one, and if one goes you can pretty much say good bye to all the data. There are recovery tools/options but they are not easy or guaranteed. I'm not trying to sound like the harbinger of doom, but I've been bitten by this myself.
LVM does raid 1 & raid 0.
But again if one volume goes you usually need to take time to rebuild the array. Then it also limited to linux.
I'd say simply scheduled copying diska -> diskb.
If you had say 3 1.5TBs raid5 would be doable.
But you would need an o/s that can do that software raid version. FreeBSD(zfs), windows server, linux, etc.
Or a hardware card, expensive, and I think that in some cases the raid array is dependent on the card. I.E. the raid card goes you need to buy that same card again to use your data.
The other thing to consider is that a majority of the cards under the 200$ price point are pci-x1. Which going back to lanes depending on version of pci-x, ranges from 250MB/s -> 1GB/s a lane. This all total, both ways. The last piece is a lot of the cards under 100$, are usually just a software raid wrapper. Making your cpu do all the heavy lifting.
Rsync
http://en.wikipedia.org/wiki/Rsync
Although rsync is best in multiples of 2, i.e. if you do 3 you need to think the partitioning scheme carefully. It will also be delayed based on how often you schedule it to run.
or
unraid
http://www.lime-technology.com/
On a consumer level is my recommendation.
Edited again just recalled the other linux tool
http://en.wikipedia.org/wiki/Mdadm